Regulations last checked for updates: Nov 23, 2024

Title 40 - Protection of Environment last revised: Nov 21, 2024
§ 421.250 - Applicability: Description of the primary precious metals and mercury subcategory.

The provisions of this subpart are applicable to discharges resulting from the production of gold, silver, or mercury by primary precious metals and mercury facilities.

§ 421.251 - Specialized definitions.

For the purpose of this subpart the general definitions, abbreviations, and methods of analysis set forth in 40 CFR part 401 shall apply to this subpart.

§ 421.252 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available.

Except as provided in 40 CFR 125.30 through 125.32, any existing point source subject to this subpart shall achieve the following effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable technology currently available:

(a) Smelter wet air pollution control.

BPT Limitations for the Primary Precious Metals and Mercury Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/troy ounce of gold and silver smelted
Lead0.5460.260
Mercury0.3250.130
Silver0.5330.221
Zinc1.8980.793
Gold0.130
Oil and grease26.00015.600
Total suspended solids53.30025.350
pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(b) Silver chloride reduction spent solution.

BPT Limitations for the Primary Precious Metals and Mercury Subcategory

Pollutant of pollutant property Maximum for any 1 day Maximum for monthly average
mg/troy ounce of silver reduced in solution
Lead0.1680.080
Mercury0.1000.040
Silver0.1640.068
Zinc0.5840.244
Gold0.040
Oil and grease8.0004.800
Total suspended solids16.4007.800
pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(c) Electrolytic cells wet air pollution control.

BPT Limitations for the Primary Precious Metals and Mercury Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/troy ounce of gold refined electrolytically
Lead83.16039.600
Mercury49.50019.800
Silver81.18033.660
Zinc289.100120.800
Gold19.800
Oil and grease3,960.0002,376.000
Total suspended solids8,118.0003,861.000
pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(d) Electrolyte preparation wet air pollution control.

BPT Limitations for the Primary Precious Metals and Mercury Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/troy ounce of silver in electrolyte produced
Lead0.0210.010
Mercury0.0130.005
Silver0.0210.009
Zinc0.0730.031
Gold0.005
Oil and Grease1.0000.600
Total suspended solids2.0500.975
pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(e) Calciner wet air pollution control.

BPT Limitations for the Primary Precious Metals and Mercury Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of mercury condensed
Lead78.20037.240
Mercury46.55018.620
Silver76.34031.650
Zinc271.900113.600
Gold18.600
Oil and Grease3,724.0002,234.000
Total suspended solids7,634.0003,631.000
pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(f) Calcine quench water.

BPT Limitations for the Primary Precious Metals and Mercury Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of mercury condensed
Lead7.3923.520
Mercury4.4001.760
Silver7.2162.992
Zinc25.70010.740
Gold1.760
Oil and Grease352.000211.200
Total suspended solids721.600343.200
pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(g) Calciner stack gas contact cooling water.

BPT Limitations for the Primary Precious Metals and Mercury Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of mercury condensed
Lead1.7430.830
Mercury1.0380.415
Silver1.7020.706
Zinc6.0592.532
Gold0.415
Oil and Grease83.00049.800
Total suspended solids170.20080.930
pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(h) Condenser blowdown.

BPT Limitations for the Primary Precious Metals and Mercury Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of mercury condensed
Lead5.7962.760
Mercury3.4501.380
Silver5.6582.346
Zinc20.1508.418
Gold1.380
Oil and Grease276.000165.600
Total suspended solids565.800269.100
pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(i) Mercury cleaning bath water.

BPT Limitations for the Primary Precious Metals and Mercury Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of mercury condensed
Lead0.5880.280
Mercury0.3500.140
Silver0.5740.238
Zinc2.0440.854
Gold0.140
Oil and Grease28.00016.800
Total suspended solids57.40027.300
pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

§ 421.253 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the application of the best available technology economically achievable.

Except as provided in 40 CFR 125.30 through 125.32, any existing point source subject to this subpart shall achieve the following effluent limitations representing the degree of effluent reduction attainable by the application of the best available technology economically achievable:

(a) Smelter wet air pollution control.

BAT Limitations for the Primary Precious Metals and Mercury Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/troy ounce of gold and silver smelted
Lead0.3640.169
Mercury0.1950.078
Silver0.3770.156
Zinc1.3260.546
Gold0.130

(b) Silver chloride reduction spent solution.

BAT Limitations for the Primary Precious Metals and Mercury Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/troy ounce of silver reduced in solution
Lead0.1120.052
Mercury0.0600.024
Silver0.1160.048
Zinc0.4080.168
Gold0.040

(c) Electrolytic cells wet air pollution control.

BAT Limitations for the Primary Precious Metals and Mercury Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/troy ounce of gold refined electrolytically
Lead5.5442.574
Mercury2.9701.188
Silver5.7422.376
Zinc20.2008.316
Gold1.980

(d) Electrolyte preparation wet air pollution control.

BAT Limitations for the Primary Precious Metals and Mercury Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/troy ounce of silver in electrolyte produced
Lead0.0140.007
Mercury0.0080.003
Silver0.0150.006
Zinc0.0510.021
Gold0.005

(e) Calciner Wet Air Pollution Control.

BAT Limitations for the Primary Precious Metals and Mercury Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of mercury condensed
Lead6.1602.860
Mercury3.3001.320
Silver6.3802.640
Zinc22.4409.240
Gold2.200

(f) Calcine quench water.

BAT Limitations for the Primary Precious Metals and Mercury Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of mercury condensed
Lead4.9282.288
Mercury2.6401.056
Silver5.1042.112
Zinc17.9507.392
Gold1.760

(g) Calciner stack gas contact cooling water.

BAT Limitations for the Primary Precious Metals and Mercury Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of mercury condensed
Lead1.1620.540
Mercury0.6230.249
Silver1.2040.498
Zinc4.2331.743
Gold0.415

(h) Condenser blowdown.

BAT Limitations for the Primary Precious Metals and Mercury Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of mercury condensed
Lead3.8641.794
Mercury2.0700.828
Silver4.0021.656
Zinc14.0805.796
Gold1.380

(i) Mercury cleaning bath water.

BAT Limitations for the Primary Precious Metals and Mercury Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of mercury condensed
Lead0.3920.182
Mercury0.2100.084
Silver0.4060.168
Zinc1.4280.588
Gold0.140
§ 421.254 - Standards of performance for new sources.

Any new source subject to this subpart shall achieve the following new source performance standards:

(a) Smelter wet air pollution control.

NSPS for the Primary Precious Metals and Mercury Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/troy ounce of gold and silver smelted
Lead0.3640.169
Mercury0.1950.078
Silver0.3770.156
Zinc1.3260.546
Gold0.130
Oil and Grease13.00013.000
Total suspended solids19.50015.600
pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(b) Silver chloride reduction spent solution.

NSPS for the Primary Precious Metals and Mercury Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/troy ounce of silver reduced in solution
Lead0.1120.052
Mercury0.0600.024
Silver0.1160.048
Zinc0.4080.168
Gold0.040
Oil and Grease4.0004.000
Total suspended solids6.0004.800
pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(c) Electrolytic cells wet air pollution control.

NSPS for the Primary Precious Metals and Mercury Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/troy ounce of gold refined electrolytically
Lead5.5442.574
Mercury2.9701.188
Silver5.7422.376
Zinc20.2008.316
Gold1.980
Oil and Grease198.000198.000
Total suspended solids297.000237.600
pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(d) Electrolyte preparation wet air pollution control.

NSPS for the Primary Precious Metals and Mercury Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/troy ounce of silver in electrolyte produced
Lead0.0140.007
Mercury0.0080.003
Silver0.0150.006
Zinc0.0510.021
Gold0.005
Oil and Grease0.5000.500
Total suspended solids0.7500.600
pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(e) Calciner wet air pollution control.

NSPS for the Primary Precious Metals and Mercury Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of mercury condensed
Lead6.1602.860
Mercury3.3001.320
Silver6.3802.640
Zinc22.4409.240
Gold2.200
Oil and Grease220.000220.000
Total suspended solids330.000264.000
pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(f) Calcine quench water.

NSPS for the Primary Precious Metals and Mercury Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of mercury condensed
Lead4.9282.288
Mercury2.6401.056
Silver5.1042.112
Zinc17.9507.392
Gold1.760
Oil and Grease176.000176.000
Total suspended solids264.000211.200
pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(g) Calciner stack gas contract cooling water.

NSPS for the Primary Precious Metals and Mercury Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) or mercury condensed
Lead1.1620.540
Mercury0.6230.249
Silver1.2040.498
Zinc4.2331.743
Gold0.415
Oil and Grease41.50041.500
Total suspended solids62.25049.800
pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(h) Condenser blowdown.

NSPS for the Primary Precious Metals and Mercury Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of mercury condensed
Lead3.8641.794
Mercury2.0700.828
Silver4.0021.656
Zinc14.0805.796
Gold1.380
Oil and Grease138.000138.000
Total suspended solids207.000165.600
pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(i) Mercury cleaning bath water.

NSPS for the Primary Precious Metals and Mercury Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of Mercury condensed
Lead0.3920.182
Mercury0.2100.084
Silver0.4060.168
Zinc1.4280.588
Gold0.140
Oil and Grease14.00014.000
Total suspended solids21.00016.800
pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

[50 FR 38361, Sept. 20, 1985; 50 FR 41144, Oct. 9, 1985]
§ 421.255 - [Reserved]
§ 421.256 - Pretreatment standards for new sources.

Except as provided in 40 CFR 403.7, any new source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve the following pretreatment standards for new sources. The mass of wastewater pollutants in primary precious metals and mercury process wastewater introduced into a POTW shall not exceed the following values:

(a) Smelter wet air pollution control.

PSNS for the Primary Precious Metals and Mercury Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/troy ounce of gold and silver smelted
Lead0.3640.169
Mercury0.1950.078
Silver0.3770.156
Zinc1.3260.546
Gold0.130

(b) Silver chloride reduction spent solution.

PSNS for the Primary Precious Metals and Mercury Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/troy ounce of silver reduced in solution
Lead0.1120.052
Mercury0.0600.024
Silver0.1160.048
Zinc0.4080.168
Gold0.040

(c) Electrolytic cells wet air pollution control.

PSNS for the Primary Precious Metals and Mercury Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/troy ounce of gold refined electrolytically
Lead5.5442.574
Mercury2.9701.188
Silver5.7422.376
Zinc20.2008.316
Gold1.980

(d) Electrolyte preparation wet air pollution control.

PSNS for the Primary Precious Metals and Mercury Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/troy ounce of silver in electrolyte produced
Lead0.0140.007
Mercury0.0080.003
Silver0.0150.006
Zinc0.0510.021
Gold0.005

(e) Calciner wet air pollution control.

PSNS for the Primary Precious Metals and Mercury Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of mercury condensed
Lead6.1602.860
Mercury3.3001.320
Silver6.3802.640
Zinc22.4409.240
Gold2.200

(f) Calcine quench water.

PSNS for the Primary Precious Metals and Mercury Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of mercury condensed
Lead4.9282.288
Mercury2.6401.056
Silver5.1042.112
Zinc17.9507.392
Gold1.760

(g) Calciner stack gas contact cooling water.

PSNS for the Primary Precious Metals and Mercury Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of mercury condensed
Lead1.1620.540
Mercury0.6230.249
Silver1.2040.498
Zinc4.2331,743
Gold0.415

(h) Condenser blowdown.

PSNS for the Primary Precious Metals and Mercury Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of mercury condensed
Lead3.8641.794
Mercury2.0700.828
Silver4.0021.656
Zinc14.0805.656
Gold1.380

(i) Mercury cleaning bath water.

PSNS for the Primary Precious Metals and Mercury Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of mercury condensed
Lead0.3920.182
Mercury0.2100.084
Silver0.4060.168
Zinc1.4280.588
Gold0.140
§ 421.257 - [Reserved]
authority: Secs. 301, 304 (b), (c), (e), and (g), 306 (b) and (c), 307 (b) and (c), 308 and 501 of the Clean Water Act (the Federal Water Pollution Control Act Amendments of 1972, as amended by the Clean Water Act of 1977) and the Water Quality Act of 1987 (the “Act”); 33 U.S.C. 1311,1314,c,e,and, 1316 (b) andc, 1317 (b) andc,1318; 86 Stat. 816, Pub. L. 92-500; 91 Stat. 1567, Pub. L. 95-217; 101 Stat. 7, Pub. L. 100-4
source: 49 FR 8790, Mar. 8, 1984, unless otherwise noted.
cite as: 40 CFR 421.252