Regulations last checked for updates: Oct 17, 2024

Title 40 - Protection of Environment last revised: Oct 15, 2024
§ 414.91 - Toxic pollutant effluent limitations and standards for direct discharge point sources that use end-of-pipe biological treatment.

(a) Any point source subject to this subpart must achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentrations in the following table.

(b) In the case of chromium, copper, lead, nickel, zinc, and total cyanide, the discharge quantity (mass) shall be determined by multiplying the concentrations listed in the following table for these pollutants times the flow from metal-bearing waste streams for the metals and times the flow from cyanide bearing waste streams for total cyanide. The metal-bearing waste streams and cyanide-bearing waste streams are defined as those waste streams listed in appendix A of this part, plus any additional OCPSF process wastewater streams identified by the permitting authority on a case-by-case basis as metal or cyanide bearing based upon a determination that such streams contain significant amounts of the pollutants identified above. Any such streams designated as metal or cyanide bearing must be treated independently of other metal or cyanide bearing waste streams unless the permitting authority determines that the combination of such streams, prior to treatment, with the appendix A waste streams will result in substantial reduction of these pollutants. This determination must be based upon a review of relevant engineering, production, and sampling and analysis information.

Effluent characteristics Effluent limitations BAT and NSPS 1
Maximum for any one day Maximum for any monthly average
Acenaphthene5922
Acenaphthylene5922
Acrylonitrile24296
Anthracene5922
Benzene13637
Benzo(a)anthracene5922
3,4-Benzofluoranthene6123
Benzo(k)fluoranthene5922
Benzo(a)pyrene6123
Bis(2-ethylhexyl) phthalate279103
Carbon Tetrachloride3818
Chlorobenzene2815
Chloroethane268104
Chloroform4621
2-Chlorophenol9831
Chrysene5922
Di-n-butyl phthalate5727
1,2-Dichlorobenzene16377
1,3-Dichlorobenzene4431
1,4-Dichlorobenzene2815
1,1-Dichloroethane5922
1,2-Dichloroethane21168
1,1-Dichloroethylene2516
1,2-trans-Dichloroethylene5421
2,4-Dichlorophenol11239
1,2-Dichloropropane230153
1,3-Dichloropropylene4429
Diethyl phthalate20381
2,4-Dimethylphenol3618
Dimethyl phthalate4719
4,6-Dinitro-o-cresol27778
2,4-Dinitrophenol12371
2,4-Dinitrotoluene285113
2,6-Dinitrotoluene641255
Ethylbenzene10832
Fluoranthene6825
Fluorene5922
Hexachlorobenzene2815
Hexachlorobutadiene4920
Hexachloroethane5421
Methyl Chloride19086
Methylene Chloride8940
Naphthalene5922
Nitrobenzene6827
2-Nitrophenol6941
4-Nitrophenol12472
Phenanthrene5922
Phenol2615
Pyrene6725
Tetrachloroethylene5622
Toluene8026
Total Chromium2,7701,110
Total Copper3,3801,450
Total Cyanide1,200420
Total Lead690320
Total Nickel3,9801,690
Total Zinc 22,6101,050
1,2,4-Trichlorobenzene14068
1,1,1-Trichloroethane5421
1,1,2-Trichloroethane5421
Trichloroethylene5421
Vinyl Chloride268104

1 All units are micrograms per liter.

2 Total Zinc for Rayon Fiber Manufacture that uses the viscose process and Acrylic Fiber Manufacture that uses the zinc chloride/solvent process is 6,796 µg/l and 3,325 µg/l for maximum for any one day and maximum for monthly average, respectively.

[52 FR 42568, Nov. 5, 1987, as amended at 58 FR 36892, July 9, 1993]
authority: Secs. 301, 304, 306, 307, and 501, Pub. L. 92-500, 86 Stat. 816, Pub. L. 95-217, 91 Stat. 156, Pub. L. 100-4, 101 Stat. 7 (33 U.S.C. 1311,1314,1316,1317,and
source: 52 FR 42568, Nov. 5, 1987, unless otherwise noted.
cite as: 40 CFR 414.91