Regulations last checked for updates: Oct 18, 2024

Title 40 - Protection of Environment last revised: Oct 16, 2024
§ 421.220 - Applicability: Description of the secondary molybdenum and vanadium subcategory.

The provisions of this subpart are applicable to discharges resulting from the production of molybdenum or vanadium by secondary molybdenum and vanadium facilities.

§ 421.221 - Specialized definitions.

For the purpose of this subpart the general definitions, abbreviations, and methods of analysis set forth in 40 CFR part 401 shall apply to this subpart.

§ 421.222 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available.

Except as provided in 40 CFR 125.30 through 125.32, any existing point source subject to this subpart shall achieve the following effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable technology currently available:

(a) Leach tailings.

BPT Limitations for the Secondary Molybdenum and Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of technical grade molybdenum plus vanadium plus pure grade molybdenum produced
Arsenic40.77818.145
Chromium8.5853.512
Lead8.1953.902
Nickel37.46024.779
Iron23.41011.902
Molybdenum[Reserved][Reserved]
Ammonia (as N)8078.0003551.000
Total Suspended Solids799.950380.460
pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(b) Molybdenum filtrate solvent extraction raffinate.

BPT Limitations for the Secondary Molybdenum and Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of technical grade molybdenum plus vanadium plus pure grade molybdenum produced
Arsenic121.72054.162
Chromium25.62510.483
Lead24.46011.648
Nickel111.81973.964
Iron69.88735.526
Molybdenum[Reserved][Reserved]
Ammonia (as N)24114.00010600.000
Total Suspended Solids2387.8001135.660
pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(c) Vanadium decomposition wet air pollution control.

BPT Limitations for the Secondary Molybdenum and Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of vanadium produced by decomposition
Arsenic0.0000.000
Chromium0.0000.000
Lead0.0000.000
Nickel0.0000.000
Iron0.0000.000
Molybdenum0.0000.000
Ammonia (as N)0.0000.000
Total suspended solids0.0000.000
pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(d) Molybdenum drying wet air pollution control.

BPT Limitations for the Secondary Molybdenum and Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of molybdenum produced
Arsenic0.0000.000
Chromium0.0000.000
Lead0.0000.000
Nickel0.0000.000
Iron0.0000.000
Molybdenum0.0000.000
Ammonia (as N)0.0000.000
Total suspended solids0.0000.000
pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(e) Pure Grade Molybdenum.

BPT Limitations for the Secondary Molybdenum and Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of pure molybdenum produced
Arsenic48.65521.650
Chromium10.2434.190
Lead9.7784.656
Nickel44.69829.566
Iron27.93614.201
Molybdenum[Reserved][Reserved]
Ammonia (as N)9638.0004237.000
Total Suspended Solids954.480453.960
pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

[50 FR 38357, Sept. 20, 1985, as amended at 55 FR 31703, Aug. 3, 1990]
§ 421.223 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the application of the best available technology economically achievable.

Except as provided in 40 CFR 125.30 through 125.32, any existing point source subject to this subpart shall achieve the following effluent limitations representing the degree of effluent reduction attainable by the application of the best available technology economically achievable:

(a) Leach Tailings.

BAT Limitations for the Secondary Molybdenum and Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of technical grade molybdenum plus vanadium plus pure grade molybdenum produced
Arsenic27.12012.097
Chromium7.2192.927
Lead5.4632.536
Nickel10.7317.219
Iron23.41311.902
Molybdenum[Reserved][Reserved]
Ammonia (as N)8078.0003551.000

(b) Molybdenum filtrate solvent extraction raffinate.

BAT Limitations for the Secondary Molybdenum and Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of technical grade molybdenum plus vanadium plus pure grade molybdenum produced
Arsenic80.95236.108
Chronium21.5488.736
Lead16.3067.571
Nickel32.03121.548
Iron69.88735.526
Molybdenum[Reserved][Reserved]
Ammonia (as N)24114.00010600.000

(c) Vanadium decomposition wet air pollution control.

BAT Limitations for the Secondary Molybdenum and Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of vanadium produced by decomposition
Arsenic0.0000.000
Chromium0.0000.000
Lead0.0000.000
Nickel0.0000.000
Iron0.0000.000
Molybdenum0.0000.000
Ammonia (as N)0.0000.000

(d) Molybdenum drying wet air pollution control.

BAT Limitations for the Secondary Molybdenum and Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of molybdenum produced
Arsenic0.0000.000
Chromium0.0000.000
Lead0.0000.000
Nickel0.0000.000
Iron0.0000.000
Molybdenum0.0000.000
Ammonia (as N)0.0000.000

(e) Pure Grade Molybdenum.

BAT Limitations for the Secondary Molybdenum and Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of pure molybdenum produced
Arsenic32.35914.434
Chromium8.6143.492
Lead6.5183.026
Nickel12.8048.614
Iron27.93614.201
Molybdenum[Reserved][Reserved]
Ammonia (as N)9638.0004237.000
[50 FR 38357, Sept. 20, 1985, as amended at 55 FR 31703, 31704, Aug. 3, 1990]
§ 421.224 - Standards of performance for new sources.

Any new source subject to this subpart shall achieve the following new source performance standards:

(a) Leach tailings.

NSPS for the Secondary Molybdenum and Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of technical grade molybdenum plus vanadium plus pure grade molybdenum produced
Arsenic27.12012.097
Chromium7.2192.927
Lead5.4632.536
Nickel10.7317.219
Iron23.41311.902
Molybdenum[Reserved][Reserved]
Ammonia (as N)8078.0003551.000
Total Suspended Solids292.665234.132
pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(b) Molybdenum filtrate solvent extraction raffinate.

NSPS for the Secondary Molybdenum and Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of technical grade molybdenum plus vanadium plus pure grade molybdenum produced
Arsenic80.95236.108
Chromium21.5488.736
Lead16.3067.571
Nickel32.03121.548
Iron69.88735.526
Molybdenum[Reserved][Reserved]
Ammonia (as N)24114.00010600.000
Total Suspended Solids873.585698.868
pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(c) Vanadium decomposition wet air pollution control.

NSPS for the Secondary Molybdenum and Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of molybdenum and vanadium produced
Arsenic0.0000.000
Chromium0.0000.000
Lead0.0000.000
Nickel0.0000.000
Iron0.0000.000
Molybdenum0.0000.000
Ammonia (as N)0.0000.000
Total suspended solids0.0000.000
pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(d) Molybdenum drying wet air pollution control.

NSPS for the Secondary Molybdenum and Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of molybdenum and vanadium produced
Arsenic0.0000.000
Chromium0.0000.000
Lead0.0000.000
Nickel0.0000.000
Iron0.0000.000
Molybdenum0.0000.000
Ammonia (as N)0.0000.000
Total suspended solids0.0000.000
pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(e) Pure Grade Molybdenum.

NSPS for the Secondary Molybdenum and Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of pure molybdenum produced
Arsenic32.35914.434
Chromium8.6143.492
Lead6.5183.026
Nickel12.8048.614
Iron27.93614.201
Molybdenum[Reserved][Reserved]
Ammonia (as N)9638.0004237.000
Total Suspended Solids349.200279.360
pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

[50 FR 38357, Sept. 20, 1985, as amended at 55 FR 31704, Aug. 3, 1990]
§ 421.225 - [Reserved]
§ 421.226 - Pretreatment standards for new sources.

Except as provided in 40 CFR 403.7, any new source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve the following pretreatment standards for new sources. The mass of wastewater pollutants in secondary molybdenum and vanadium process wastewater introduced into a POTW shall not exceed the following values:

(a) Leach tailings.

PSNS for the Secondary Molybdenum and Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of technical grade molybdenum plus vanadium plus pure grade molybdenum produced
Arsenic27.12012.097
Chromium7.2192.927
Lead5.4632.536
Nickel10.7317.219
Iron23.41311.902
Molybdenum[Reserved][Reserved]
Ammonia (as N)8078.0003551.000

(b) Molybdenum filtrate solvent extraction raffinate.

PSNS for the Secondary Molybdenum And Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of technical grade molybdenum plus vanadium plus pure grade molybdenum produced
Arsenic80.95236.108
Chromium21.5488.736
Lead16.3067.571
Nickel32.03121.548
Iron69.88735.526
Molybdenum[Reserved][Reserved]
Ammonia (as N)24114.00010600.000

(c) Vanadium decomposition wet air pollution control.

PSNS for the Secondary Molybdenum and Vandadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) vanadium produced by decomposition
Arsenic0.0000.000
Chromium0.0000.000
Lead0.0000.000
Nickel0.0000.000
Iron0.0000.000
Molybdenum0.0000.000
Ammonia (as N)0.0000.000

(d) Molybdenum drying wet air pollution control.

PSNS for the Secondary Molybdenum and Vandadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of molybdenum produced
Arsenic0.0000.000
Chromium0.0000.000
Lead0.0000.000
Nickel0.0000.000
Iron0.0000.000
Molybdenum0.0000.000
Ammonia (as N)0.0000.000

(e) Pure Grade Molybdenum.

PSNS for the Secondary Molybdenum And Vanadium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average
mg/kg (pounds per million pounds) of pure molybdenum produced
Arsenic32.35914.434
Chromium8.6143.492
Lead6.5183.026
Nickel12.8048.614
Iron27.93614.201
Molybdenum[Reserved][Reserved]
Ammonia (as N)9638.0004237.000
[50 FR 38357, Sept. 20, 1985, as amended at 55 FR 31704, 31705 Aug. 3, 1990]
§ 421.227 - [Reserved]
authority: Secs. 301, 304 (b), (c), (e), and (g), 306 (b) and (c), 307 (b) and (c), 308 and 501 of the Clean Water Act (the Federal Water Pollution Control Act Amendments of 1972, as amended by the Clean Water Act of 1977) and the Water Quality Act of 1987 (the “Act”); 33 U.S.C. 1311,1314,c,e,and, 1316 (b) andc, 1317 (b) andc,1318; 86 Stat. 816, Pub. L. 92-500; 91 Stat. 1567, Pub. L. 95-217; 101 Stat. 7, Pub. L. 100-4
source: 49 FR 8790, Mar. 8, 1984, unless otherwise noted.
cite as: 40 CFR 421.223